Bi2O3 modification of HZSM-5 for methanol-to-propylene conversion: evidence of olefin-based cycle
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Conversion of Methanol to Propylene over a High Silica B-HZSM-5 Catalyst
Hydrothermally synthesized high silica borosilicates with the MFI structure was subjected to several characterization techniques. The effect of boron on the structure and acidity of HZSM-5 catalyst were studied by XRD, SEM, N2 adsorption, solid state NMR, NH3-TPD. It was confirmed that boron had entered the framework in the boron samples. The results also revealed that strong acidity was weaken...
متن کاملNear-Graphite Coke Deposit on Nano-HZSM-5 Aggregates for Methanol to Propylene and Butylene Reaction
Nanocrystal HZSM-5 zeolite aggregates with different SiO2/Al2O3 molar ratios were prepared under low temperature and were used to catalyze the conversion of methanol to propylene and butene. The coke location, coke content, and coke species deposited on HZSM-5 aggregates were investigated. The near-graphite carbon on the external surface of HZSM-5 zeolite (SiO2/Al2O3 molar ratio = 400) was dist...
متن کاملCatalytic Conversion of Methanol to Hydrocarbons over different wt% Ni-HZSM-5
Due to crude oil is limited, new resources for fuel and petrochemicals are important to be developed. Biogas or NG (Natural Gas) can be easily converted into methanol which can be reacted over zeolite to produce olefins and gasoline. HZSM-5 zeolite catalyst has been used in this study and its modification by (0.5wt%, 1wt%, 2wt% and 4wt %) Ni to convert methanol to hydrocarbons (MTH). Catalysts ...
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a novel and ultra low cost isfet electrode and measurement system was designed for isfet application and detection of hydronium, hydrazinium and potassium ions. also, a measuring setup containing appropriate circuits, suitable analyzer (advantech board), de noise reduction elements, cooling system and pc was used for controlling the isfet electrode and various characteristic measurements. the t...
Catalytic Conversion of Acetone to Monoaromatic Chemicals using HZSM-5
The effects of process variables (temperature, space velocity, water addition and Si/Al ratio) on the conversion of acetone to aromatic chemicals have been investigated. The reaction is carried out by fixed bed reactor at an atmospheric pressure to examine the activity and selectivity of HZSM-5. The results show that HZSM-5 exhibited a high active and a shape-selective catalyst for the formatio...
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ژورنال
عنوان ژورنال: RSC Advances
سال: 2017
ISSN: 2046-2069
DOI: 10.1039/c6ra27849c